Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-Tiidos and Fineman-Ross methods. The reactivity ratios were found to be rAM A = 2.35, rBM A = 0.08 (Kelen-Tiidos) and rAM A = 2.37, rnMA = 0.08 (Fineman-Ross).
Посилання на статтю:
Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate / H. CatalgiI-Giz, N. Uyamk and C. Erbil // Polymer. – 1992. – Vol 33. – P. 655-656.