The miscibility and domain structure of poly(vinyl alcohol)/poly(vinylpyrrolidone) (PVA/PVP) blends are investigated by high-resolution solid-state 13C nuclear magnetic resonance methods. The observed 13C spectra and the intermolecular cross-polarization of the blends suggest a hydrogen-bonding interaction between the two polymers, aH T1 and T1o results indicate that the blends are miscible at all compositions on a scale of 200-300 A. On a scale of 20-30 A, however, the miscibility of the blends depends significantly on the composition. When the PVA composition is more than 46 wt%, the blends are composed of two phases, an amorphous miscible phase of PVP plus PVA and a pure PVA phase. The crystallinity of the PVA phase decreases rapidly with decreasing PVA composition. When the PVA composition is less than 46 wt%, the blend is completely miscible. The composition of PVA phase in the blends was inferred from the results of ~H Tip.
Посилання на статтю:
High-resolution solid-state 13C nuclear magnetic resonance study on poly(vinyl alcohol ) / poly (vinylpyrrolidone) blends / Xiaoqing Zhang*, K. Takegoshi and Kunio Hikichi // Polymer. – 1992. – Vol 33. – P. 712-717.