3C n.m.r, spin-lattice relaxation times have been determined for carbons in a number of solid alkanes and in two linear polyethylenes. ~3C spin-lattice relaxation times, Tls, for the internal methylene carbons of the linear alkanes depend upon structure and chain length. There is almost a 100-fold increase in T1 in going from orthorhombic C2~H44 to C6oH~22. The central methylene carbons in the two polyethylenes give rise to two exponential decays. Analysis of the methyl resonances in one of these polyethylenes suggests that 60% of the methyl ends are in a crystalline environment. Low molecular weight orthorhombic alkanes are more mobile than expected from the 1 / T~ versus a dimension of the unit cell relationship observed for linear and branched polyethylenes
Посилання на статтю:
13C n.m.r, and X-ray diffraction studies of the morphology of alkanes and linear polyethylenes / K. E. Russell, Gang Wu, S. Blake and R. D. Heyding // Polymer. – 1992. – Vol 33. – P. 951-957.