2-Hydroxy-4-methacryloxyacetophenone (2H4MAP) was prepared and polymerized in methyl ethyl ketone using benzoyl peroxide as initiator. Poly (2H4MAP) was characterized by infra-red and 1H nuclear magnetic resonance spectroscopic techniques. The molecular weight of the polymer was determined by gel permeation chromatography. Cu(II) and Ni(n) chelates of poly(2H4MAP) were synthesized. Elemental analysis of the polychelates suggests a metal-to-ligand ratio of 1:2. The polychelates were further characterized by infra-red and electronic spectral studies, and electrical conductivity measurements. Thermogravimetric analysis of the polychelates has been carried out in air.
Посилання на статтю:
Polymer-metal complexes: 1. Synthesis and characterization of poly(2-hydroxy-4- methacryloxyacetophenone)-metal complexes / S. Thamizharasi and A. Venkata Rami Reddy // Polymer. – 1992. – Vol 33. – P. 2421-2423.