A statistical thermodynamics theory of a polydisperse polymer based on a lattice model of a fluid is formulated. The pure polydisperse polymer is completely characterized by three scale factors and the distribution law of the system. The equation of state does not satisfy a simple corresponding state principle, except for the polymer fluid with sufficiently high molecular weight.
Посилання на статтю:
Statistical thermodynamics of a lattice fluid: pure polymer / Lijia An, Rongtang Ma, Xichun Kou and Xinyi Tang // Polymer. – 1992. – Vol 33. – P. 2855-2856.