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A new t-BOC protected monomer, N-(tert-butyloxycarbonyl)maleimide (t-BOCMI) 3 was synthesized by thermolysis in a high yield and a new kind of t-BOC protected polymer was prepared by radical copolymerization, t-BOCMI and styrene derivatives (X-St) were readily copolymerized to obtain alternating copolymers of P(t-BOCMI/X-St) 5 in high conversions. The t-BOCMI units of the t-BOC protected copolymers were converted to the maleimide (MI) units by heating at about 150°C or above, releasing 2-methylpropene and carbon dioxide. The facile deprotection of the side-chain t-BOC groups from the protected copolymers was attained to bring about a large polarity change. The deprotected copolymers P(MI/Y-St) 6 have very high glass transition temperatures (T~s) of about 250°C and good solubility in aqueous base solutions, whereas the t-BOC polymers P(t-BOCMI/X-St) are only soluble in organic solvents. The t-BOC protected maleimide polymers were found to have specific properties for application as chemically amplified resist materials such as alkaline solubility, high Tg and facile deprotection.

Посилання на статтю:

Synthesis and polymerization of N-( tert-butyloxycarbonyl )maleimide and facile deprotection of polymer side-chain t-BOC groups / Kwang-Duk Ahn*, Young-Hun Lee and Deok-II Koo // Polymer. – 1992. – Vol 33. – P. 4851-4856.

Synthesis and polymerization of N-( tert-butyloxycarbonyl )maleimide and facile deprotection of polymer side-chain t-BOC groups - Завантажити.