AM! calculations are reported for enines with aromatic substituents. It was found that the position of the unsaturated bonds in each molecule may account for the reactivity of each isomer via different polymerization pathways. The resonant structure of the charged form of one of the molecules allowed speculation about the observed inhibition of the polymerization reaction.
Посилання на статтю:
Chemical pathways for the polymerization of enines / Roberto Salcedo, Takeshi Ogawat, Armando Pinedat,Manuel F. Rubio-Arroyo$,Monserrat Garcia§ and Patricia Guadarrama // Polymer. – 1992. – Vol 33. – P. 5300-5302.