This paper reports the synthesis and polymerization of a new methacrylamide derivative, N-[4-(4-methoxyphenylacetyloxy)phenyl]methacrylamide, which supports functional side groups of potential biomedical interest. Polymers obtained by free radical polymerization in a solution of N,N-dimethylformamide at moderate temperatures were characterized by 1H and aaC n.m.r., being predominantly syndiotactic, with an isotacticity parameter or=0.19, somewhat lower than that of poly(methyl methacrylate) (PMMA, tr = 0.22) or poly[N-(4-methacryloyloxyphenyl)2, -(4-methoxyphenyl)- acetamide][poly(OM), a=0.27]. This behaviour seems to be a consequence of the stiffness of the methacrylamide side groups with respect to the methacrylic ester function of poly(OM) and PMMA
Посилання на статтю:
Synthesis and characterization of a new poly(methacrylamide) bearing side groups of biomedical interest / Alberto Gallardo and Julio San Roman // Polymer. – 1993. – Vol 34. – P. 394-400.