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The photolysis of catena-poly(phenyl-4-phenylphenylsilicon) at ki,c = 365-400nm leads to products (probably free radicals) which are oxidized by diphenyliodonium ions. The resulting ionic species is capable of readily initiating the cationic polymerization of tetrahydrofuran, n-butyl vinyl ether, cyclohexene oxide and N-vinylcarbazol.

Посилання на статтю:

Long wavelength photoinitiated cationic polymerization using diphenyliodonium salt and catena-poly (phenyl-4-phenylphenylsilicon / Yusuf Yagci*, Ivan Kminekt and Wolfram Schnabel // Polymer. – 1993. – Vol 34. – P. 426-428.

Long wavelength photoinitiated cationic polymerization using diphenyliodonium salt and catena-poly (phenyl-4-phenylphenylsilicon - Завантажити.