Deposition of polypyrrole tosylate, synthesized potentiostatically with values of 0.5-0.8 V (relative to a standard calomel electrode) from an aqueous solution, on a solid non-conducting surface in a specially designed thin-layer cell led to the observation of two-dimensional growth of the film directly adjacent to the surface, reverting to three-dimensional dendritic growth as the film thickness increases. The significance of the two forms of morphology is discussed
Посилання на статтю:
Formation of surface-modified polypyrrole films by electropolymerization on non-conducting solid surfaces / J. S. Shapiro* and W. T. Smith // Polymer. – 1993. – Vol 34. – P. 4336-4340.