The room temperature crystal structures, unit cell dimensions at ll0 K and phase transitions of three poly(p-phenylene) oligomers are reported. The structures of p-quinquephenyl (PQP), C3oH22 , p-sexiphenyl (PSP), C36H26 , and p-septiphenyl (PSeptiP), C42H30, each belonging to space group P21/c, are similar to those of shorter oligomers. The unit cell dimensions are a = 22.056 A, b = 5.581 A, c = 8.070 A and/~ = 97.91 ° for PQP, a=26.241A, b=5.568A, c=8.09lA and /~=98.17 ° for PSP, and a=30.577A, b=5.547A, c=8.034A and fl=100.52 ° for PSeptiP. The a axis increases with molecular length. The molecules are linear and planar in all three structures. The herringbone nature of the packing is similar for PQP and PSeptiP, while a considerably greater tilt occurs in PSP. At 110 K, the unit cell parameters b and c are approximately doubled while a remains nearly the same as in the room temperature cell. A time-dependent solid state transition is observed for PQP, PSP and PSeptiP when crystals are cooled to 110 K. At elevated temperatures, thermal measurements indicate the oligomers to be thermotropic liquid crystals. The crystal smectic transition temperatures are reported for PQP, PSP, PSeptiP and p-octiphenyl (POP), C4sH34. The results of a molecular mechanics study on the conformation and packing of PSP are also presented. The competition between intramolecular forces (such as ortho hydrogen repulsions) and intermolecular crystal packing forces was examined in particular. Molecular mechanics calculations predict non-planar conformations in isolated polyphenyls, implying that conjugation between phenyl rings is insufficient to overcome ortho hydrogen repulsions. In a crystalline environment, however, intermolecular forces tend to force a planar conformation. Calculations on arrays of PSP molecules show that changing the phenyl-phenyl torsion angles from the coplanar value increases the total energy of the structure. The most favourable intermolecular interactions between oligomers are achieved for conformations having the phenyl rings coplanar.
Посилання на статтю:
Crystal structures, phase transitions and energy calculations of poly(p-phenylene) oligomers / Kenneth N. Baker, Albert V. Fratini, Timothy Resch andHoward C. Knachel and W. W. Adams and E. P. Socci and B. L. Farmer // Polymer. – 1993. – Vol 34. – P. 1571-1587.