This work deals with the reaction of succinoylated dextran with glycidyl acetate (a model compound of glycidyl bioactive derivative) using benzyltriethylammonium chloride as catalyst. The reaction shows second order kinetics and depends on the glycidyl acetate and catalyst concentrations, showing no dependence on the acid groups' concentration. On the basis of these findings a probable mechanism of the reaction is suggested.
Посилання на статтю:
Kinetic aspects of the reaction of succinoylated dextran with glycidyl acetate / Felix Arranz*, Manuel S&nchez-Chaves and Juan Carlos Ramirez // Polymer. – 1993. – Vol 34. – P. 1908-1912.