Physicochemical phenomena at the polymer-metal interface have been observed by the use of surfaceenhanced Raman scattering (SERS). SERS spectra are compared with the infra-red reflection-absorption spectra for coatings of polymer on metals. Results show that SERS is an effective in situ analytical technique which is highly informative in that the authentic adsorption state and the microstructure of the first monolayer near the metal surface can be revealed with much less interference from the polymer bulk.
Посилання на статтю:
Surface-enhanced Raman scattering used as an in situ analytical method for studies of polymer-metal interface / G. Xue*, Y. Lu and G. Shi // Polymer. – 1994. – Vol 35. – P. 2488-2494.