The copolymerization behaviour of the adduct of N',N'-dimethylaminopropyl methacrylamide and epichlorohydrin (DMAPMA-Epi) and methyl methacrylate (MMA) was investigated. The reactivity ratios for the MMA (I)/DMAPMA-Epi (2) couple in solution, using various regression methods based on the Mayo-Lewis model, are r 1 --- 1.73 and r2 =0.03. The Q and e values for DMAPMA-Epi are estimated to be 0.23 and - 1.32 respectively. On the basis of the reactivity ratios, theoretical curves for the instantaneous copolymer composition throughout conversion have been calculated
Посилання на статтю:
Copolymerization of a novel substituted methacrylamide with methyl methacrylate / Dax Kukulj, Thomas P. Davis* and Robert P. Burford // Polymer. – 1994. – Vol 35. – P. 3579-3582.