Poly(methylphenylsilane) has been synthesized through homogeneous reductive dechlorination of dichloromethylphenylsilane using sodium/electron-acceptor complexes in tetrahydrofuran solution at -79°C. The optimization of product molecular weights is considered through analogy to a step-growth polymerization
Посилання на статтю:
The formation of polysilanes from homogeneous reagents in tetrahydrofuran solution at low temperatures / Richard G. Jones*, Robert E. Benfield, R. Harry Cragg, Philip J. Evans andAnthony C. Swain // Polymer. – 1994. – Vol 35. – P. 4924-4926.