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An FT-i.r. method was used to investigate the thermal cyclization process in synthesis of polyesterimidazopyrrolones from diesterdianhydrides and 3,3 0 -diaminobenzidine. It was proved that the structure of diphenols in the diesterdianhydrides influences the cyclization which goes via an amino-imide to the imidazopyrrolone structure. The presence of an electron-donating group in the diphenol causes the beginning of cyclization at a lower temperature than in the case when in the diesterdianhydride there is a diphenol with electron-withdrawing group. The cyclization process was investigated by dynamic and isothermal heating.

Посилання на статтю:

FT-i.r. study of thermal cyclization processes in synthesis of polyesterimidazopyrrolones / Danuta Sȩk, Bożena Kaczmarczyk, Ewa Schab-Balcerzak // Polymer. – 1999. – N 40. – P. 4493–4504.

FT-i.r. study of thermal cyclization processes in synthesis of polyesterimidazopyrrolones - Завантажити.