A series of semifluorinated fluorocarbon/hydrocarbon di- and triblock copolymers were prepared by atom transfer radical polymerization (ATRP). The mono- and difunctional macroinitiators, which were obtained from bulk ATRP of styrene, butyl acrylate and methyl acrylate, initiated solution ATRP of 2-[(perfluorononenyl)oxy]ethyl methacrylate and ethylene glycol mono-methacrylate mono-perfluorooctanoate, respectively. The formation of the block copolymer was confirmed with size exclusion chromatography and 1H NMR spectrum.
Посилання на статтю:
Polymer Communication Synthesis of fluorine-containing block copolymers via ATRP 2. Synthesis and characterization of semifluorinated di- and triblock copolymers q / Z.-B. Zhang, S.-K. Ying, Z.-Q. Shi // Polymer. – 1999. – N 40. – P. 5439–5444.