The polymerization of new sulfur containing spiro orthocarbonates with the ability to undergo double ring-opening is reported. Various initiators were used in the cationic polymerization study, and the polymer structure determined. The polymerization is proposed to occur via a controlled tandem double ring-opening mechanism.
Посилання на статтю:
The double ring-opening polymerization of sulfur containing spiro orthocarbonates / Mark K. Bromley, David H. Solomon // Polymer. – 1999. – N 40. – P. 6539–6543.